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Abstract: The effect of a plasticizer dimethyl formamide (DMF) on the properties of a sodium ion conducting
electrolyte based on poly(methyl-methacrylate) (PMMA) complexed with sodium perchlorate (NaClO4)
prepared using solution cast technique was investigated. The features of complexation of the electrolytes were
studied by X-ray diffraction. Film morphology was examined by Scanning Electron Microscopy (SEM). Various
experimental techniques, such as electrical conductivity (temperature dependence) and transference number
measurements were used to characterize these polymer electrolyte films. Transference number data show that
the charge transference in this polymer electrolyte system is predominantly due to ions. Electrochemical cells of
configuration Na/PMMA+NaClO4/(I2+C+electrolyte)andNa/PMMA+NaClO4+plasticizer /(I2+C+electrolyte)
were fabricated. The discharge characteristics of the cells were studied under a constant load of 100 kΩ. The
open-circuit voltage, short-circuit current and discharge time for the plateau region were measured. The
PMMA+NaClO4 polymer electrolyte system with added plasticizer showed an increased discharge time with
respect to pure PMMA+NaClO4 electrolyte system..
,
Key words:Polymer electrolyte, XRD, SEM, Electrical conductivity, Transference number and Discharge profile
Key words:Polymer electrolyte, XRD, SEM, Electrical conductivity, Transference number and Discharge profile
[1] S. Ramesh, Geok Bee The, Rong-Fuh Louh, Yong Kong Hou, Pung Yen Sin, and Lim Jing Yi, "Preparation and
characterization of plasticized high molecular weight PVC based polymer electrolytes", Indian Academy of Sciences, 35, 2010,
pp. 87-95.
[2] B. Santhos Kadam, Kunal Datta, Prasanta Ghosh, and D. Mahendra Shisat, "Poly(pyrrole)-Poly(N-Methylpyrrole) Composite
Matrix for Amperometric Biosensor Design" International journal of Polymeric Materials, 60, 2011, pp. 233-243.
[3] P. Santhosh , T. Vasudevan, A. Gopalan, and K. P. Lee, "Preparation and properties of new cross-linked polyurethane acrylate
electrolytes for lithium batteries", J. Power Sources, 160, 2006, pp. 609-620.
[4] S. Rajendran, R. Kannan, and O. Mahendran, "An electrochemical investigation on PMMA/PVdF blend-based polymer
electrolytes", Mater Lett., 49, 2001, pp. 172-179.
[5] M. Sivakumar, R. Subadevi, S. Rajendran, H. –C. Wu, and N. –L. Wu, "Compositional effect of pvdF – PEMA blend gel
polymer electrolytes for Lithium Polymer Batteries", European Polymer Journal, 43, 2007, pp. 4466-4473.
[6] L.Paskal, L. Linets, V. Syromrpntnikov, and V. Pushiko, "Studies of Li-complexes with acrylonitrile copolymers by the
dielectric method" Solid State Ionics, 147, 2002, pp.383-390.
[7] S. Rajendran, M. Sivakumar, and R. Subadevi, "Investigations on the effect of various plasticizers in PVA–PMMA solid polymer
blend Electrolytes" Materials Letters,58, 2004, pp. 641 – 649.
[8] M. Sundar, and S. Selladurai, "Effect of Fillers on Magnesium- Poly(Ethylene Oxide) Solid Polymer Electrolyte", Ionics,12,
2006, pp. 281- 286.
[9] D. K. Pradhan, R. N. P. Choudhary, and B. K. Samantaray, "Studies of dielectric and electrical properties of plasticized polymer
nanocomposite electrolytes", Materials Chemistry and Physics, 115, 2009, pp. 557- 561.
[10] H. W. Chen, T. P. Lin, and F. C. Chang, "Ionic conductivity enhancement of the plasticized PMMA/LiClO4 polymer", Polymer,
43, 2002, pp. 5281-5288.
characterization of plasticized high molecular weight PVC based polymer electrolytes", Indian Academy of Sciences, 35, 2010,
pp. 87-95.
[2] B. Santhos Kadam, Kunal Datta, Prasanta Ghosh, and D. Mahendra Shisat, "Poly(pyrrole)-Poly(N-Methylpyrrole) Composite
Matrix for Amperometric Biosensor Design" International journal of Polymeric Materials, 60, 2011, pp. 233-243.
[3] P. Santhosh , T. Vasudevan, A. Gopalan, and K. P. Lee, "Preparation and properties of new cross-linked polyurethane acrylate
electrolytes for lithium batteries", J. Power Sources, 160, 2006, pp. 609-620.
[4] S. Rajendran, R. Kannan, and O. Mahendran, "An electrochemical investigation on PMMA/PVdF blend-based polymer
electrolytes", Mater Lett., 49, 2001, pp. 172-179.
[5] M. Sivakumar, R. Subadevi, S. Rajendran, H. –C. Wu, and N. –L. Wu, "Compositional effect of pvdF – PEMA blend gel
polymer electrolytes for Lithium Polymer Batteries", European Polymer Journal, 43, 2007, pp. 4466-4473.
[6] L.Paskal, L. Linets, V. Syromrpntnikov, and V. Pushiko, "Studies of Li-complexes with acrylonitrile copolymers by the
dielectric method" Solid State Ionics, 147, 2002, pp.383-390.
[7] S. Rajendran, M. Sivakumar, and R. Subadevi, "Investigations on the effect of various plasticizers in PVA–PMMA solid polymer
blend Electrolytes" Materials Letters,58, 2004, pp. 641 – 649.
[8] M. Sundar, and S. Selladurai, "Effect of Fillers on Magnesium- Poly(Ethylene Oxide) Solid Polymer Electrolyte", Ionics,12,
2006, pp. 281- 286.
[9] D. K. Pradhan, R. N. P. Choudhary, and B. K. Samantaray, "Studies of dielectric and electrical properties of plasticized polymer
nanocomposite electrolytes", Materials Chemistry and Physics, 115, 2009, pp. 557- 561.
[10] H. W. Chen, T. P. Lin, and F. C. Chang, "Ionic conductivity enhancement of the plasticized PMMA/LiClO4 polymer", Polymer,
43, 2002, pp. 5281-5288.
- Citation
- Abstract
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Abstract:Nickel substituted CoxZn0.8-x Fe2O4 (x=0.2,0.5 and 0.6) ferrite were synthesized by Sol-gel auto
combustion method. The powders were sintering at 400oc and 700oc for 2hrs to densify properly. The samples
were characterized by XRD, SEM and FTIR and Magnetic properties. The XRD used to analyze phase structure
and lattice parameters. The FTIR spectra confirmed that synthesis material is ferrite. Morphology of ferrite
powders were investigated by using SEM. Porosity of synthesis ferrite is measured. The saturation
magnetization increases with increasing Co-Zn concentration. Resistivity of ferrite material is may be decreases
due to vary concentration of Co and Zn.
Keywords: Nanocrystalline, Structural Properties, Sol-gel Auto Combustion method, XRD, FTIR, SEM, Magnetization, Resistivity.
Keywords: Nanocrystalline, Structural Properties, Sol-gel Auto Combustion method, XRD, FTIR, SEM, Magnetization, Resistivity.
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[3] K.C.Varma et al(2011), Strl, Microstrl.,Mag. Prop. Of NiCoMn Ferite thin film, J.Of Mag.and Mat.,323,3271-3275.
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[8] R.Bhise S.Rathod, A.Supekar (2012 ) Synt. of Ni-Co-Zn ferrite nanoparticles, Int. J. of Basic and Appl. Res., 44(168-172).
[9] R.Bhise, S.Rathod, A.Supekar (2012), Char. of nanocryst. Ni-Co-Zn ferrite Powd., Golden Research Thoughts, Vol. 2 Iss. 4.
[2] B.K.Chaughale(010), Prep. Char. Mag. Prop. Of nanocrystalline Ni Zn Ferrite, Sch.Res.Lib.2(2),388-395.
[3] K.C.Varma et al(2011), Strl, Microstrl.,Mag. Prop. Of NiCoMn Ferite thin film, J.Of Mag.and Mat.,323,3271-3275.
[4] K.H.Buschow,(1995),Hnd.bk Of Mag. Mat,8,198.
[5] M.Stefanescu,(2009), Prepn. Of Ni Zn Micro Comp. Powd. By S-G, j of Mat. Chem. And app. Phy.,113,342-348.
[6] P.K.Roy,(2008),Chr. Of nano Cryst. Ferritr, J. of Mat. Process Tec.,197,279-283.
[7] Xqi,J.Zhou,(2002), Key Eng. Mat.,593,224.
[8] R.Bhise S.Rathod, A.Supekar (2012 ) Synt. of Ni-Co-Zn ferrite nanoparticles, Int. J. of Basic and Appl. Res., 44(168-172).
[9] R.Bhise, S.Rathod, A.Supekar (2012), Char. of nanocryst. Ni-Co-Zn ferrite Powd., Golden Research Thoughts, Vol. 2 Iss. 4.
- Citation
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Abstract:Single crystals of zinc succinate (ZS) with monoclinic structure were grown in silica gel medium. The
functional groups in the crystal were analyzed by FT-IR Spectroscopy. Thermal degradation studies have been
carried out by Differential Scanning Calorimetry (DSC). Dielectric constant and a c conductivity have been
estimated as a function of frequency for different temperatures.
Keywords: a c conductivity, Dielectric Property, NLO, zinc succinate
Keywords: a c conductivity, Dielectric Property, NLO, zinc succinate
[1] B. Milton Boaz, S. Jerome Das Journal of Crystal Growth 279 (2005) 383–389
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[5] Shaokang Gao, Weijun Chen, Guimei Wang, Jianzhong Chen Journal of Crystal Growth 297 (2006) 361–365
[6] Xiu-Li Wang Bao Mu, Hong-Yan Lin, Guo-Cheng Liu Journal of Organometallic Chemistry 696, 11–12, (2011) 2313–2321
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[10] M. Loganayaki, T.Bharthasarathi, P. Murugakoothan International Journal of ChemTech Research 3 (2011) 1070-1074
[2] A.Chandramohan , R.Bharathikannan, J.Chandrasekaran, P.Maadeswaran, R. Renganathan , V.Kandavelu Journal of Crystal
Growth 310 (2008) 5409–5415
[3] Vincent Crasta, V. Ravindrachary, R.F. Bhajantri, Richard Gonsalves Journal of Crystal Growth 267 (2004) 129–133
[4] G. Eazhilarasi, R. Nagalakshmi, V. Krishnakumar Spectrochimica Acta Part A 71 (2008) 502–507
[5] Shaokang Gao, Weijun Chen, Guimei Wang, Jianzhong Chen Journal of Crystal Growth 297 (2006) 361–365
[6] Xiu-Li Wang Bao Mu, Hong-Yan Lin, Guo-Cheng Liu Journal of Organometallic Chemistry 696, 11–12, (2011) 2313–2321
[7] Y.T. Wang, H.H. Fan, H.Z. Wang, X.M. Chen, Inorg. Chem. 44(2005) 4148.
[8] Y. Kang, Y.G. Yao, Y.Y. Qin, J. Zhang, Y.B. Chen, Z.J. Li,Y.H. Wen, J.K. Cheng, R.F. Hu, Chem. Commun. 9 (2004) 1046
[9] Jianguo Pan, Gongjun Zhang, Yueqing Zheng, Jianli Lin, Wei Xu Journal of Crystal Growth 308 (2007) 89–92
[10] M. Loganayaki, T.Bharthasarathi, P. Murugakoothan International Journal of ChemTech Research 3 (2011) 1070-1074
