IOSR-JAGG   Volume-1 ~ Issue-6 ~ NOV-DEC-2013

Abstract: The thermal maturity parameter used in the evaluation of the hydrocarbon generative potential of the sedimentary organic matter is based largely on the extent of molecular transformation of the biological markers due to geothermal stress which is a function of depth or burial history. In particular the transformations leading to the formation of Polynuclear Aromatics usually occur at the end of diagenesis up to the onset of catagenesis. . An in-depth study of the transformation leading to the formation of polynuclear aromatic steroidal hydrocarbons revealed a step by step thermally mediated aromatization of the non-aromatic biogenic species during diagenetic/catagenetic evolution of organic matter in an anoxic environment. Since the formation of PAHs is a heat mediated process which increases with depth, then its concentration or the amount per unit mass of the rock sample can be used to estimate the thermal maturity of organic matter in the sediment .In light of the above, this work has evaluated the distribution profile of the PAHs in the Cretaceous sediments of the Calabar Flank using Gas Chromatograph interfaced to a Mass Spectrometer (GC-MS),an analytical tool combination widely used in the study of petroleum geochemistry. The results of the study based on the most dominant polynucear aromatic species namely, anthracene and phenanthrene revealed that Nkporo Shale(NS)samples from various locations in the Basin had a average PAH of 0.05mg/Kg (anthracene) and 0.06mg/Kg (phenanthrene).While the PAH value of Ekenkpon Shale(ES) samples was on the average 0.01mg/Kg and 0.02mg/Kg for anthracene and phenanthrene respectively. New Netim Marl(NNM) however gave the PAH value of only 0.001mg/Kg for phenanthrene and nil for anthracene .On the other hand Awi Sandstone (AS), Mfamosing Limestone (ML) and Nkporo Mudstone(NM) all fell within the non-detectable range. Based on the foregoing, PAH values can be used to evaluate the maturation level of organic matter in the sediments.

Keywords: Cretaceous Sediments, Polynuclear Aromatic Hydrocarbons, Thermal Maturity, Distribution Profile

Abstract: The present paper presents a new approach for total ozone column forecasting using an Artificial Neural Network technique for Baghdad, Iraq. Total ozone column data for the period (1979-2000) were used as training and the period (2009-2011) for testing and one year(2012) for forecasting also the combination of meteorological elements have been used as input parameters (stratospheric temperature, Geopotential height and zonal wind). at 50 and 70 mb respectively. The developed ANN models are being applied for aimed at providing forecasts in a near real time schedule, different network types were tested with different kinds of input information. Preliminary tests showed that a generalized feed forward ANN model using Gaussian activation function achieved the optimum forecasting of total ozone column.

Abstract:The sedimentary deposit is a part of the south of Lampang basin with the age of Tertiary to present. Clays in this deposit was divided into three layers covered with red clay. Clay layers were overburden which was the clay overlying on top of coal seam; interburden was the clays lie between coal seams; and underburden was the clay lie under coal seam. The basement rock was rhyolitic tuff. Major minerals found were quartz, kaolinite, illite, potassium feldspar and montmorillonite, respectively. There was no distinct relationship of quartz content in each clay layers. However, kaolinite and illite contents slightly increased in deeper clay layers. Additionally, montmorillonite presented in basement rock sample and some of overburden clay.

Keywords: ceramic, clays, Lampang, mineralogical, sedimentary