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Research Paper |
| Title |
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Synthesis and Characterization of New Complexes of (N-P-Amino Diphenyl Amine) Amino (2-Hydroxy Phenyl) Acetonitrile Ligand with Some Transition Metal Ions |
| Country |
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Iraq |
| Authors |
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Ammar Jihad Alabdali |
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10.9790/5736-0320510  |
Abstract: The synthesis and characterization of new complexes of Fe(II), Co(II), Ni(II) and Cu(II) with bidentate (N-p-amino diphenyl amine) amino (2-hydroxy phenyl) acetonitrile ligand has been described .The ligand was prepared from 2-hydroxy benzaldehyde and 4-aminodiphenyl amine in the presence of KCN and acidic medium. The complexes were synthesized by treating an ethanolic solution of the ligand with appropriate amount of metal salts [1:2] [M: L] ratio. The complexes were characterized by using metal and elemental analysis, infrared and electronic spectra, molar conductivity, magnetic susceptibility, and mole ratio method. According to the obtained data the probable coordination geometries of Iron, Cobalt, Nickel and Copper in these complexes are octahedral. All complexes were found to be non-electrolyte in absolute ethanol, and the complexes were formulated as [ML2Cl2].
Keywords : α-aminonitrile, Cobalt, Copper,Complexes,Iron and Nickel.
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