Abstract::Cement kiln dust (CKD) is alkaline materials which contains solid material mixture mainly calcium oxide (CaO). The activation process of CKD was carried out with refluxing methanol at T 343.15 K for 90 minutes. The activation studies were performed based on methanol to oil weight ratio (1:1, 3:1, and 5:1). The transesterification performance studies were carried out in intensified reactor at T 343.15 K and 353.15 K with various methanol to oil mole ratios (200:1 and 300:1). It is found that CKD was activated at temperature of 340.15 – 355.15 K. Therefore, the use of CKD catalysts for transesterification at temperatures higher than355.15 Kwill not beeffective........
Keywords: activation; calciummethoxide; calcium oxide; cement kiln dust; heterogeneous catalyst; methanol; mole ratio; temperature; transesterification.
[1]. Ma F., Hanna M.A., Biodiesel Production: a review, Bioresour Technol, 70, pp. 1–15, 1999.
[2]. Freedman B., Pryde E.H., Mounts T.L., Variables Affecting The Yields of Fatty Esters from Transesterified Vegetable Oils, J Am Oil Chem Soc, 61, pp.1638-1643, 1984.
[3]. Schuchardt U., Sercheli R., Vargas R., Transesterification of Vegetable Oils: a review, J Braz Chem Soc, 9, pp. 199–210, 1998.
[4]. Fukuda H., Kondo A., Noda H., Biodiesel Fuel Production by Transesterification of Oils, J Biosci Bioeng, 92, pp. 405–416, 2001.
[5]. Cai Y., Nieweg J.A., Turner W.A., Wilkinson C.K., Systems and Processes for Biodiesel Production, Patent No. US 2011/0054200 A1, 2011.
[6]. Lin V.S., Cai Y., Kern C., Dulebohn J.I., and Nieweg J.A., Solid Catalyst System for Biodiesel Production, Patent No. US 2009/0112007 A1, 2009.